{"id":147106,"date":"2023-07-17T12:20:18","date_gmt":"2023-07-17T10:20:18","guid":{"rendered":"https:\/\/concentrol.com\/silicone-emulsions-characteristics-and-applications\/"},"modified":"2025-07-23T13:23:31","modified_gmt":"2025-07-23T11:23:31","slug":"silicone-emulsions-characteristics-and-applications","status":"publish","type":"post","link":"https:\/\/hosting175685eu-cp704.wordpresstemporal.com\/de\/silicone-emulsions-characteristics-and-applications\/","title":{"rendered":"Silicone emulsions: characteristics and applications"},"content":{"rendered":"<div class=\"wpb-content-wrapper\"><p>[vc_row][vc_column][vc_column_text uncode_shortcode_id=&#8220;147276&#8243;]<span style=\"font-weight: 400;\">An <\/span><b>emulsion<\/b><span style=\"font-weight: 400;\"> is a stable and homogeneous mixture of two insoluble or very slightly compatible liquids. Generally, one of them is water, and the other is a water-insoluble liquid, such as mineral or vegetable oil or silicone.<\/span><\/p>\n<p><span style=\"font-weight: 400;\">When these two incompatible liquids are mixed, they form two phases. With vigorous stirring, they can be mixed, but once the stirring stops, they separate quickly, resulting in the recovery of the two initial phases. Under these conditions, we would refer to it as an unstable and heterogeneous mixture.<\/span><\/p>\n<p><a href=\"https:\/\/concentrol.com\/en\/products\/silicone-emulsions\/\"><b>Silicone emulsions<\/b><\/a><span style=\"font-weight: 400;\"> are chemical formulations composed of silicone, usually in the form of silicone oil, water, and the necessary emulsifying systems to achieve a stable emulsion.<\/span><\/p>\n<p><span style=\"font-weight: 400;\">From a chemical perspective, silicone consists of a finite chain of silicon and oxygen atoms bonded together. In addition to these bonds, silicone itself has two additional bonds to organic groups. In most cases, these organic groups are methyl (CH<\/span><span style=\"font-weight: 400;\">3<\/span><span style=\"font-weight: 400;\">) groups that give silicone oil its semi-organic characteristics.<\/span><\/p>\n<p><span style=\"font-weight: 400;\">Silicone oils are inert substances, stable in the presence of water, air, oxygen, and metals. They only decompose at high temperatures and in the presence of strong mineral acids, bases, and strong oxidizing agents.<\/span><\/p>\n<p><span style=\"font-weight: 400;\">In this document, we will explore the technical characteristics of silicone emulsions, as well as the different families that exist. After providing this general framework, we will focus on the characteristics of Concentrol&#8217;s silicone emulsions, as well as their sectors and applications.<\/span><\/p>\n<p>&nbsp;<\/p>\n<p><b>Technical characteristics of silicone emulsions\u00a0\u00a0<\/b><\/p>\n<p><b>Silicone emulsions allow for easy use of a silicone, allowing for better processing and better efficacy of the final product<\/b><span style=\"font-weight: 400;\">. The most important parameters in a silicone emulsion are:<\/span><b><\/b><\/p>\n<ul>\n<li aria-level=\"1\"><b>pH<\/b><\/li>\n<\/ul>\n<p><span style=\"font-weight: 400;\">The pH of silicone emulsions is generally not a critical parameter, since non-ionic emulsifiers are commonly used. <\/span><b>Variations in pH<\/b><span style=\"font-weight: 400;\"> do not destabilize the emulsion, but they <\/span><b>can impact the final formulation<\/b><span style=\"font-weight: 400;\"> where the emulsion is incorporated. To avoid the need for adjustments in the final product, silicone emulsions are typically adjusted to a neutral pH.<\/span><\/p>\n<ul>\n<li style=\"font-weight: 400;\" aria-level=\"1\"><b>Viscosity<\/b><span style=\"font-weight: 400;\">\u00a0<\/span><\/li>\n<\/ul>\n<p><span style=\"font-weight: 400;\">Viscosity measures the fluidity of a silicone emulsion. Silicone emulsions made with silicone fluids have low or very low viscosities, typically below 1000cps, making them highly fluid products. <\/span><b>A low viscosity is indicative of a well-emulsified product <\/b><span style=\"font-weight: 400;\">with small particle sizes.<\/span><b><\/b><\/p>\n<ul>\n<li aria-level=\"1\"><b>Dry extract<\/b><\/li>\n<\/ul>\n<p><span style=\"font-weight: 400;\">Dry extract, also known as solids, refers to the percentage of non-evaporative material in the emulsion after the drying process. <\/span><b>The dry extract of a silicone emulsion is related to the quantity of the silicone content<\/b><span style=\"font-weight: 400;\">, which is the active component of this type of product. In general, silicone emulsions are formulated with a dry extract ranging between 20% and 60%.<\/span><b><\/b><\/p>\n<ul>\n<li aria-level=\"1\"><b>Filtration\u00a0<\/b><\/li>\n<\/ul>\n<p><span style=\"font-weight: 400;\">Due to their low viscosity, silicone emulsions can be <\/span><b>filtered through fine meshes, typically 250 microns or 100 microns<\/b><span style=\"font-weight: 400;\">. This characteristic allows for easy formulation in products like adhesives, varnishes, paints, or coatings without altering their desired properties.<\/span><b><\/b><\/p>\n<ul>\n<li aria-level=\"1\"><b>Stability<\/b><\/li>\n<\/ul>\n<p><span style=\"font-weight: 400;\">Well-manufactured silicone emulsions are <\/span><b>stable products<\/b><span style=\"font-weight: 400;\"> that can be stored for extended periods without separation or instability.<\/span><\/p>\n<p><span style=\"font-weight: 400;\">Certain silicone emulsions are capable of withstanding freeze-thaw cycles, making them suitable for use in very cold climates.<\/span><\/p>\n<ul>\n<li style=\"font-weight: 400;\" aria-level=\"1\"><b>Preservatives<\/b><span style=\"font-weight: 400;\">\u00a0<\/span><\/li>\n<\/ul>\n<p><b>Preservatives such as isothiazolinones <\/b><span style=\"font-weight: 400;\">(BIT, MIT and\/or CMIT), <\/span><b>formaldehyde releasers <\/b><span style=\"font-weight: 400;\">and other additives like <\/span><b>bronopol<\/b><span style=\"font-weight: 400;\"> are commonly used in silicone emulsions. Food preservatives such as sorbates and benzoates may be used in specific versions of silicone emulsions, resulting in an acidic pH.<\/span><b><\/b><\/p>\n<ul>\n<li aria-level=\"1\"><b>Particle size\u00a0<\/b><\/li>\n<\/ul>\n<p><span style=\"font-weight: 400;\">Silicone emulsions typically have <\/span><b>small particle sizes<\/b><span style=\"font-weight: 400;\">, which is directly linked to their stability. The smaller the particle size, the more stable the emulsion tends to be.<\/span><b><\/b><\/p>\n<ul>\n<li aria-level=\"1\"><b>Free monomer<\/b><\/li>\n<\/ul>\n<p><span style=\"font-weight: 400;\">Some silicone emulsions <\/span><b>may contain free silicone monomers<\/b><span style=\"font-weight: 400;\">, which are volatile or semi-volatile compounds. These monomers can be analyzed using gas chromatography.<\/span><b><\/b><\/p>\n<ul>\n<li aria-level=\"1\"><b>Wetting<\/b><\/li>\n<\/ul>\n<p><span style=\"font-weight: 400;\">Silicones can sometimes cause <\/span><b>wetting issues due to their inherent properties<\/b><span style=\"font-weight: 400;\">. When used in coatings, they may lead to uneven coverage or surface defects.<\/span><b><\/b><\/p>\n<ul>\n<li aria-level=\"1\"><b>Toxicity<\/b><\/li>\n<\/ul>\n<p><span style=\"font-weight: 400;\">Silicone oil, the main component of silicone emulsions, is <\/span><b>not considered toxic or dangerous<\/b><span style=\"font-weight: 400;\">. Discharging silicone emulsions into wastewater typically does not pose significant problems, as the silicone settles with the purification sludge, resulting in non-classified residue.<\/span><\/p>\n<p>&nbsp;<\/p>\n<p><b>Emulsion families\u00a0\u00a0<\/b><\/p>\n<p><span style=\"font-weight: 400;\">Silicone emulsions are classified into two groups based on particle size: silicone macroemulsions and silicone microemulsions.<\/span><\/p>\n<p><b>Silicone macroemulsions<\/b><span style=\"font-weight: 400;\">, also referred to as <\/span><b>ES-type silicone emulsions<\/b><span style=\"font-weight: 400;\">, exhibit the following characteristics:<\/span><\/p>\n<ul>\n<li style=\"font-weight: 400;\" aria-level=\"1\"><b>They have a whitish appearance and remain stable during storage<\/b><span style=\"font-weight: 400;\">. They are formulated with preservatives that ensure microbiological stability for over 6 months. The silicone content can vary.<\/span><\/li>\n<li style=\"font-weight: 400;\" aria-level=\"1\"><span style=\"font-weight: 400;\">The average particle size ranges from <\/span><b>0.1 to 1 micron<\/b><span style=\"font-weight: 400;\">.<\/span><\/li>\n<li style=\"font-weight: 400;\" aria-level=\"1\"><span style=\"font-weight: 400;\">These emulsions can contain up to <\/span><b>60% silicone<\/b><span style=\"font-weight: 400;\">.<\/span><\/li>\n<li style=\"font-weight: 400;\" aria-level=\"1\"><b>Various viscosities<\/b><span style=\"font-weight: 400;\"> of silicone oil can be used in their formulation, with <\/span><b>350 cps and 1000 cps being the most common<\/b><span style=\"font-weight: 400;\">. A typical formulation has a dry extract of 35%, although a higher dry extract of 65% is also common.<\/span><\/li>\n<li style=\"font-weight: 400;\" aria-level=\"1\"><span style=\"font-weight: 400;\">After application, once the water evaporates, the silicone remains on the external surface, offering benefits such as reducing the coefficient of dynamic friction and providing a <\/span><b>lubricating effect<\/b><span style=\"font-weight: 400;\">.<\/span><\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n<p><b>Silicone microemulsions<\/b><span style=\"font-weight: 400;\">, also known as <\/span><b>EMPOL-type silicone emulsions<\/b><span style=\"font-weight: 400;\">, possess the following characteristics:<\/span><\/p>\n<ul>\n<li style=\"font-weight: 400;\" aria-level=\"1\"><b>They have a translucent appearance and exhibit high stability, even in extreme conditions. <\/b><span style=\"font-weight: 400;\">They are formulated with preservatives that ensure microbiological stability for more than 6 months.<\/span><\/li>\n<li style=\"font-weight: 400;\" aria-level=\"1\"><span style=\"font-weight: 400;\">These emulsions have a very small mean particle diameter, typically ranging from <\/span><b>0.5 to 0.2 microns<\/b><span style=\"font-weight: 400;\">.<\/span><\/li>\n<li style=\"font-weight: 400;\" aria-level=\"1\"><span style=\"font-weight: 400;\">Silicone oil used in microemulsions generally has a <\/span><b>very high viscosity, exceeding 100,000 cps<\/b><span style=\"font-weight: 400;\">. The dry extract is around 40%.\u00a0<\/span><\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n<p><b>Concentrol silicone emulsions<\/b><\/p>\n<p><span style=\"font-weight: 400;\">Concentrol silicone emulsions offer several advantages when used as <\/span><b>components in other chemical formulations<\/b><span style=\"font-weight: 400;\">. These advantages include:<\/span><\/p>\n<ul>\n<li style=\"font-weight: 400;\" aria-level=\"1\"><span style=\"font-weight: 400;\">Good thermal and dilution <\/span><b>stability<\/b><span style=\"font-weight: 400;\">.<\/span><\/li>\n<li style=\"font-weight: 400;\" aria-level=\"1\"><b>Compatible with soaps or anionic and non-ionic surfactants<\/b><span style=\"font-weight: 400;\">. Easy application, does not yellow after time.<\/span><\/li>\n<li style=\"font-weight: 400;\" aria-level=\"1\"><b>Good surface wetting<\/b><span style=\"font-weight: 400;\"> characteristics.<\/span><\/li>\n<li style=\"font-weight: 400;\" aria-level=\"1\"><b>High brightness and color intensity<\/b><span style=\"font-weight: 400;\">.<\/span><\/li>\n<li style=\"font-weight: 400;\" aria-level=\"1\"><b>Good slip characteristics<\/b><span style=\"font-weight: 400;\"> and improves abrasion resistance.<\/span><\/li>\n<li style=\"font-weight: 400;\" aria-level=\"1\"><span style=\"font-weight: 400;\">Provides a <\/span><b>natural finish to the textile fiber<\/b><span style=\"font-weight: 400;\">.<\/span><\/li>\n<li style=\"font-weight: 400;\" aria-level=\"1\"><span style=\"font-weight: 400;\">It can be used as a <\/span><b>lubricant<\/b><span style=\"font-weight: 400;\"> in sewing machines to reduce needle temperature, thus improving wear resistance and minimizing thread breakage.<\/span><\/li>\n<\/ul>\n<p><span style=\"font-weight: 400;\">\u00a0<\/span><\/p>\n<p><b>Sectors and applications of Concentrol&#8217;s references<\/b><\/p>\n<p><span style=\"font-weight: 400;\">Concentrol solutions can be used in different professional sectors, such as:<\/span><\/p>\n<ul>\n<li aria-level=\"1\"><b>Textile and leather<\/b><\/li>\n<li aria-level=\"1\"><b>Adhesive Manufacturers<\/b><\/li>\n<li aria-level=\"1\"><b>Paper manufacturers<\/b><\/li>\n<li aria-level=\"1\"><b>Inks<\/b><\/li>\n<li aria-level=\"1\"><b>Pressure sensitive adhesives<\/b><\/li>\n<li aria-level=\"1\"><b>Paintings<\/b><\/li>\n<\/ul>\n<p><span style=\"font-weight: 400;\">Silicone emulsions find various applications in different professional sectors, including:<\/span><\/p>\n<p>&nbsp;<\/p>\n<ul>\n<li aria-level=\"1\"><b>Polishing Additives<\/b><\/li>\n<\/ul>\n<p><span style=\"font-weight: 400;\">Silicone emulsions are used as additives in polish formulations. The <\/span><b>high gloss and light-reflecting properties<\/b><span style=\"font-weight: 400;\"> of silicone oils contribute to an enhanced shine on smooth surfaces. Emulsions are easily incorporated into formulations, and even in small dosages (&lt;1%), they significantly increase the shine of the final polish product.\u00a0<\/span><\/p>\n<p><span style=\"font-weight: 400;\">This characteristic is used in formulations such as metal polishes, where products such as <\/span><b>EMULTROL ES-115-60<\/b><span style=\"font-weight: 400;\"> and <\/span><b>EMULTROL ES-115-35<\/b><span style=\"font-weight: 400;\"> can be used.<\/span><\/p>\n<p>&nbsp;<\/p>\n<ul>\n<li aria-level=\"1\"><b>Anti-Seize Additives and Lubricants\u00a0<\/b><\/li>\n<\/ul>\n<p><span style=\"font-weight: 400;\">Silicone oils&#8216; non-stick properties make them suitable as <\/span><b>anti-seize additives and lubricants<\/b><span style=\"font-weight: 400;\">. They can be used as mold release agents for plastics and polymers, such as rubber and polyurethane shoe soles or tires. Prior testing is recommended to ensure compatibility with the specific materials.<\/span><\/p>\n<p><span style=\"font-weight: 400;\">Silicone oils are also employed as <\/span><b>lubricants to reduce friction<\/b><span style=\"font-weight: 400;\"> and minimize heat generation between materials in prolonged and intense contact. They are commonly used in conveyor belts as lubricating and anti-adherent agents, ensuring minimal silicone residue remains on the belt.<\/span><\/p>\n<p>&nbsp;<\/p>\n<ul>\n<li aria-level=\"1\"><b>Hydrophobic Additives\u00a0<\/b><\/li>\n<\/ul>\n<p><span style=\"font-weight: 400;\">Silicone emulsions can <\/span><b>increase the hydrophobicity <\/b><span style=\"font-weight: 400;\">of a product due to the insolubility of silicones in water. Incorporating silicone into a formulation enhances its resistance to water. However, it&#8217;s important to note that the hydrophobic character provided by silicone emulsions is temporary, as it depends on the balance between the silicone oil&#8217;s hydrophobicity and the hydrophilicity of the emulsifiers used.<\/span><\/p>\n<p>&nbsp;<\/p>\n<ul>\n<li aria-level=\"1\"><b>Additives in Textile Formulations and Skin Treatment\u00a0<\/b><\/li>\n<\/ul>\n<p><span style=\"font-weight: 400;\">Silicone emulsions are utilized to achieve various characteristics in textiles and skin treatments, including <\/span><b>wear resistance, hydrophobicity, gloss enhancement, and softness<\/b><span style=\"font-weight: 400;\">. They provide an <\/span><b>elastomeric finish<\/b><span style=\"font-weight: 400;\"> to textile fibers, imparting a natural and soft touch. In oven-cured fabrics, silicone emulsions <\/span><b>increase resistance to elongation<\/b><span style=\"font-weight: 400;\">. They are also employed in high dilution for <\/span><b>ironing facilitation<\/b><span style=\"font-weight: 400;\">, thanks to their softening and lubricating effects. In leather treatment, silicone emulsions with high thermal stability <\/span><b>enhance abrasion resistance and provide shine<\/b><span style=\"font-weight: 400;\"> in final aqueous formulations. They are also used to <\/span><b>improve slip<\/b><span style=\"font-weight: 400;\"> and create a <\/span><b>greasy finish<\/b><span style=\"font-weight: 400;\"> in leather treatment without leaving residue or staining.<\/span><\/p>\n<p>&nbsp;<\/p>\n<p><span style=\"font-weight: 400;\">Concentrol ranges<\/span><b> EMULTROL ES<\/b><span style=\"font-weight: 400;\"> and <\/span><b>EMULTROL PS<\/b><span style=\"font-weight: 400;\"> are commonly used in these applications.<\/span><\/p>\n<ul>\n<li aria-level=\"1\"><b>Additives in Adhesive Formulations, Particularly Pressure-Sensitive Adhesives:\u00a0<\/b><\/li>\n<\/ul>\n<p><span style=\"font-weight: 400;\">Silicone emulsions find use in adhesive formulations, particularly in the production of self-adhesive paper. The small particle size of silicone emulsions allows for <\/span><b>good wetting of the liquid adhesive<\/b><span style=\"font-weight: 400;\"> when applied to paper. This is crucial in industrial-scale processes where a minimal amount of adhesive is applied at high speed with low thickness. Good wetting ensures high process efficiency.\u00a0<\/span><\/p>\n<p><b>EMULTROL PS <\/b><span style=\"font-weight: 400;\">and <\/span><b>EMULTROL ES <\/b><span style=\"font-weight: 400;\">emulsion references are commonly employed in adhesive applications.<\/span><\/p>\n<p>&nbsp;<\/p>\n<p><b>Concentrol<\/b><span style=\"font-weight: 400;\"> is a company dedicated to innovation in chemistry, aiming to create value and ensure the well-being of society both now and in the future. The professionals at Concentrol are committed to continuous improvement, constantly working to enhance their existing products and develop new ones that address the real needs of various professional sectors.<\/span>[\/vc_column_text][\/vc_column][\/vc_row][vc_row][vc_column width=&#8220;1\/1&#8243;][vc_button border_width=&#8220;0&#8243; link=&#8220;url:https%3A%2F%2Fconcentrol.com%2Fwp-content%2Fuploads%2F2023%2F07%2FEN_Emulsions-silicona.pdf|target:_blank&#8220; uncode_shortcode_id=&#8220;762026&#8243;]Download infographic[\/vc_button][vc_column_text uncode_shortcode_id=&#8220;134655&#8243;]<div class=\"wp-block-pdfemb-pdf-embedder-viewer\"><a href=\"https:\/\/concentrol.com\/wp-content\/uploads\/2023\/07\/EN_Emulsions-silicona.pdf\" class=\"pdfemb-viewer\" style=\"\" data-width=\"max\" data-height=\"max\" data-toolbar=\"bottom\" data-toolbar-fixed=\"off\">EN_Emulsions-silicona<\/a><\/div>[\/vc_column_text][\/vc_column][\/vc_row]<\/p>\n<\/div>","protected":false},"excerpt":{"rendered":"<p>[vc_row][vc_column][vc_column_text uncode_shortcode_id=&#8220;147276&#8243;]An emulsion is a stable and homogeneous mixture of two insoluble or very slightly compatible liquids. Generally, one of [&hellip;]<\/p>\n","protected":false},"author":24,"featured_media":147088,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"_acf_changed":false,"content-type":"","footnotes":""},"categories":[650],"tags":[],"class_list":["post-147106","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-additives-de-2"],"acf":[],"yoast_head":"<!-- This site is optimized with the Yoast SEO plugin v28.0 - https:\/\/yoast.com\/product\/yoast-seo-wordpress\/ -->\n<title>Silicone emulsions: characteristics and applications<\/title>\n<meta name=\"description\" content=\"Concentrol - Chemical Solutions\" \/>\n<meta name=\"robots\" content=\"index, follow, max-snippet:-1, max-image-preview:large, max-video-preview:-1\" \/>\n<link rel=\"canonical\" href=\"https:\/\/concentrol.com\/de\/silicone-emulsions-characteristics-and-applications\/\" \/>\n<meta property=\"og:locale\" content=\"de_DE\" \/>\n<meta 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