{"id":160718,"date":"2024-10-31T16:41:52","date_gmt":"2024-10-31T14:41:52","guid":{"rendered":"https:\/\/concentrol.com\/?p=160718"},"modified":"2025-07-23T12:29:02","modified_gmt":"2025-07-23T10:29:02","slug":"improving-hydrophobicity-of-waterborne-coatings-with-wax-emulsion-additives","status":"publish","type":"post","link":"https:\/\/hosting175685eu-cp704.wordpresstemporal.com\/zh-hans\/improving-hydrophobicity-of-waterborne-coatings-with-wax-emulsion-additives\/","title":{"rendered":"Improving hydrophobicity of waterborne coatings with wax emulsion additives\u00a0"},"content":{"rendered":"<div class=\"wpb-content-wrapper\"><p>[vc_row][vc_column][vc_column_text uncode_shortcode_id=&#8221;703790&#8243;]<\/p>\n<p>An emulsion is a two-phase system of immiscible liquids. Depending on the composition of the continuous and dispersed phase, an oil-in-water emulsion or water-in-oil emulsions could be obtained. The addition of a surfactant is essential for the stability of all emulsions, serving to reduce the interfacial tension between the two liquids. Whereas other additives might be used to increase this stability.<\/p>\n<p>Wax emulsions provide a useful means of delivering wax to a product, as they are easily incorporated into waterborne coatings and paints formulations by simple mixing due to their liquid form. Waxes are typical additives that significantly influence the surface properties of any coating to improve and protect its appearance.<\/p>\n<p>Due to the chemical structure of waxes, one of the most remarkable improvements attained with these additives is water repellency. As the name implies, this characteristic is the protection of a surface against water penetration, source of mould problems (which are unhealthy and unattractive) or even irreversible structural damage.<\/p>\n<p>Usually, paraffin waxes perform very well, particularly on porous surfaces, because they are mainly composed of straight alkane chains and have good crystalline structure, giving excellent barrier effects against water.<\/p>\n<p>The range of EMULTROL wax emulsions wraps a variety of waxes like paraffin, polyethylene, lignite, carnauba, etc. that in combination with different emulsifiers covers most of the requirements of our customers. Among all, we can pinpoint EMULTROL CM-2469 SPL and CM-2655 E as the most appropriate candidates for improving water repellency in waterborne paints. Both, paraffin wax emulsions, exhibit white appearance, low particle size (&lt; 1 \u00b5m), low viscosity and alkaline pH (see Figure 1 and Table 1).<\/p>\n<p style=\"text-align: center;\"><b>Figure 1 &#8211;<\/b> EMULTROL CM-2469 SPL and CM-2655 E appearance and their corresponding particle size distribution.<\/p>\n<h5 style=\"text-align: center;\"><img decoding=\"async\" class=\" wp-image-160664 aligncenter\" src=\"https:\/\/concentrol.com\/wp-content\/uploads\/2024\/10\/Captura-de-pantalla-2024-10-31-a-las-12.09.29.png\" alt=\"\" width=\"762\" height=\"289\" srcset=\"https:\/\/hosting175685eu-cp704.wordpresstemporal.com\/wp-content\/uploads\/2024\/10\/Captura-de-pantalla-2024-10-31-a-las-12.09.29.png 1328w, https:\/\/hosting175685eu-cp704.wordpresstemporal.com\/wp-content\/uploads\/2024\/10\/Captura-de-pantalla-2024-10-31-a-las-12.09.29-300x114.png 300w, https:\/\/hosting175685eu-cp704.wordpresstemporal.com\/wp-content\/uploads\/2024\/10\/Captura-de-pantalla-2024-10-31-a-las-12.09.29-1024x389.png 1024w, https:\/\/hosting175685eu-cp704.wordpresstemporal.com\/wp-content\/uploads\/2024\/10\/Captura-de-pantalla-2024-10-31-a-las-12.09.29-768x291.png 768w, https:\/\/hosting175685eu-cp704.wordpresstemporal.com\/wp-content\/uploads\/2024\/10\/Captura-de-pantalla-2024-10-31-a-las-12.09.29-350x133.png 350w\" sizes=\"(max-width: 762px) 100vw, 762px\" \/><\/h5>\n<p style=\"text-align: center;\"><span class=\"TextRun SCXW257479141 BCX4\" lang=\"EN-GB\" xml:lang=\"EN-GB\" data-contrast=\"auto\"><span class=\"NormalTextRun SCXW257479141 BCX4\">T<\/span><span class=\"NormalTextRun SCXW257479141 BCX4\">able <\/span><span class=\"NormalTextRun SCXW257479141 BCX4\">1<\/span><\/span><span class=\"TextRun SCXW257479141 BCX4\" lang=\"EN-GB\" xml:lang=\"EN-GB\" data-contrast=\"auto\"><span class=\"NormalTextRun SCXW257479141 BCX4\"> &#8211; <\/span><\/span><span class=\"TextRun SCXW257479141 BCX4\" lang=\"EN-GB\" xml:lang=\"EN-GB\" data-contrast=\"auto\"><span class=\"NormalTextRun SCXW257479141 BCX4\">EMULTROL CM-2469 SPL and<\/span> <span class=\"NormalTextRun SCXW257479141 BCX4\">CM-2655 <\/span><span class=\"NormalTextRun SCXW257479141 BCX4\">E <\/span><span class=\"NormalTextRun SCXW257479141 BCX4\">properties<\/span><span class=\"NormalTextRun SCXW257479141 BCX4\">.<\/span><\/span><span class=\"EOP SCXW257479141 BCX4\" data-ccp-props=\"{&quot;335551550&quot;:2,&quot;335551620&quot;:2}\">\u00a0<\/span><\/p>\n<h5 style=\"text-align: center;\"><img decoding=\"async\" class=\" wp-image-160671 aligncenter\" src=\"https:\/\/concentrol.com\/wp-content\/uploads\/2024\/10\/Captura-de-pantalla-2024-10-31-a-las-12.14.02.png\" alt=\"\" width=\"676\" height=\"208\" srcset=\"https:\/\/hosting175685eu-cp704.wordpresstemporal.com\/wp-content\/uploads\/2024\/10\/Captura-de-pantalla-2024-10-31-a-las-12.14.02.png 800w, https:\/\/hosting175685eu-cp704.wordpresstemporal.com\/wp-content\/uploads\/2024\/10\/Captura-de-pantalla-2024-10-31-a-las-12.14.02-300x92.png 300w, https:\/\/hosting175685eu-cp704.wordpresstemporal.com\/wp-content\/uploads\/2024\/10\/Captura-de-pantalla-2024-10-31-a-las-12.14.02-768x236.png 768w, https:\/\/hosting175685eu-cp704.wordpresstemporal.com\/wp-content\/uploads\/2024\/10\/Captura-de-pantalla-2024-10-31-a-las-12.14.02-350x108.png 350w\" sizes=\"(max-width: 676px) 100vw, 676px\" \/><\/h5>\n<p><b>Study\u00a0<\/b><\/p>\n<p>The examination of the interaction of a liquid with a surface can provide a simple but effective evidence about the surface\u2019s characteristics and how it will perform in other related environments. Water droplet contact angle can provide an insightful information of a surface that has been tailored to exhibit desirable functions by the addition of coatings.<\/p>\n<p>A droplet that remains round, exhibiting a high contact angle (see Figure 2, left), reveals a hydrophobic or water repelling surface. On the other hand, when a droplet lies flat and wets the surface (see Figure 2, right) disclosing a low water droplet contact angle, indicates a hydrophilic surface.<\/p>\n<p>&nbsp;<\/p>\n<p style=\"text-align: center;\"><b>Figure 2<\/b> &#8211; Coated (left) and uncoated (right) surfaces to improve hydrophobicity.<\/p>\n<h5 style=\"text-align: center;\"><img decoding=\"async\" class=\"alignnone size-full wp-image-160677\" src=\"https:\/\/concentrol.com\/wp-content\/uploads\/2024\/10\/Captura-de-pantalla-2024-10-31-a-las-12.15.33.png\" alt=\"\" width=\"500\" height=\"222\" srcset=\"https:\/\/hosting175685eu-cp704.wordpresstemporal.com\/wp-content\/uploads\/2024\/10\/Captura-de-pantalla-2024-10-31-a-las-12.15.33.png 500w, https:\/\/hosting175685eu-cp704.wordpresstemporal.com\/wp-content\/uploads\/2024\/10\/Captura-de-pantalla-2024-10-31-a-las-12.15.33-300x133.png 300w, https:\/\/hosting175685eu-cp704.wordpresstemporal.com\/wp-content\/uploads\/2024\/10\/Captura-de-pantalla-2024-10-31-a-las-12.15.33-350x155.png 350w\" sizes=\"(max-width: 500px) 100vw, 500px\" \/><\/h5>\n<p>For the evaluation of the hydrophobic behaviour of each product, a layer of each of the emulsions was applied (30 \u03bcm wet) on paper and allowed to dry completely (minimum 12 h at room temperature). Then, a droplet of water was carefully placed on top of this layer, in order to observe its shape.<\/p>\n<p>Furthermore, to demonstrate the beneficial effect of using wax emulsions as additives in paints, a 2 and 3 % of each emulsion have been added to two different commercially available styrene-acrylic and acrylic resins used for paints and coatings. The characteristics of those resins are shown in table 2. Then, the same procedure mentioned above was performed using the modulated resins as coating.<\/p>\n<p>&nbsp;<\/p>\n<p style=\"text-align: center;\"><b>Table 1<\/b> &#8211; Resins properties.<\/p>\n<p style=\"text-align: center;\"><img decoding=\"async\" class=\"alignnone wp-image-160683\" src=\"https:\/\/concentrol.com\/wp-content\/uploads\/2024\/10\/Captura-de-pantalla-2024-10-31-a-las-12.16.49.png\" alt=\"\" width=\"418\" height=\"196\" srcset=\"https:\/\/hosting175685eu-cp704.wordpresstemporal.com\/wp-content\/uploads\/2024\/10\/Captura-de-pantalla-2024-10-31-a-las-12.16.49.png 576w, https:\/\/hosting175685eu-cp704.wordpresstemporal.com\/wp-content\/uploads\/2024\/10\/Captura-de-pantalla-2024-10-31-a-las-12.16.49-300x141.png 300w, https:\/\/hosting175685eu-cp704.wordpresstemporal.com\/wp-content\/uploads\/2024\/10\/Captura-de-pantalla-2024-10-31-a-las-12.16.49-350x164.png 350w\" sizes=\"(max-width: 418px) 100vw, 418px\" \/><\/p>\n<p><b>Results\u00a0<\/b><\/p>\n<p>It is well known that an uncoated paper will immediately get soaked by water when its poured on it. However, when using the appropriate coating, a hydrophobic surface can be obtained. From Figure 3, we can observe how the water droplets behave on top of coated paper. As mentioned above, the hydrophobic character is emphasized with wax emulsions (a), when compared to the purely acrylic resins (b), as a more spherical shape is attained (implying a higher contact angle).<\/p>\n<p>&nbsp;<\/p>\n<p style=\"text-align: center;\"><b>Figure 3<\/b> &#8211; Water droplets on top of coated paper with a) EMULTROL CM-2469 SPL and CM-2655 E wax emulsions and b) resin 1 and resin 2.<\/p>\n<p><img decoding=\"async\" class=\"alignnone size-full wp-image-160689\" src=\"https:\/\/concentrol.com\/wp-content\/uploads\/2024\/10\/Captura-de-pantalla-2024-10-31-a-las-12.17.55.png\" alt=\"\" width=\"978\" height=\"202\" srcset=\"https:\/\/hosting175685eu-cp704.wordpresstemporal.com\/wp-content\/uploads\/2024\/10\/Captura-de-pantalla-2024-10-31-a-las-12.17.55.png 978w, https:\/\/hosting175685eu-cp704.wordpresstemporal.com\/wp-content\/uploads\/2024\/10\/Captura-de-pantalla-2024-10-31-a-las-12.17.55-300x62.png 300w, https:\/\/hosting175685eu-cp704.wordpresstemporal.com\/wp-content\/uploads\/2024\/10\/Captura-de-pantalla-2024-10-31-a-las-12.17.55-768x159.png 768w, https:\/\/hosting175685eu-cp704.wordpresstemporal.com\/wp-content\/uploads\/2024\/10\/Captura-de-pantalla-2024-10-31-a-las-12.17.55-350x72.png 350w\" sizes=\"(max-width: 978px) 100vw, 978px\" \/><\/p>\n<p>Moreover, in Figure 4, we can perceive an improvement in the hydrophobicity of the coating when using wax emulsions as additives in acrylic resins. This effect is more accentuated when using resin 2 (b), exhibiting a more round-like shape on the water droplet.\u00a0 As expected, when the dosage is increased from 2 to 3% the hydrophobicity of the surface is enhanced (Figure 5).<\/p>\n<p>&nbsp;<\/p>\n<p>Therefore, we can conclude that EMULTROL CM-2469 SPL and EMULTROL CM-2655 E are good candidates to use as wax emulsion additives for waterborne paints, especially those based on polymeric dispersions.<\/p>\n<p style=\"text-align: center;\"><b>Figure 4<\/b> &#8211; Water droplets on top of coated paper with a) purely and additivated resin 1 b) purely and additivated resin 2 with 2% of wax emulsions.<\/p>\n<h5 style=\"text-align: center;\"><img decoding=\"async\" class=\"size-full wp-image-160695 aligncenter\" src=\"https:\/\/concentrol.com\/wp-content\/uploads\/2024\/10\/Captura-de-pantalla-2024-10-31-a-las-12.19.13.png\" alt=\"\" width=\"970\" height=\"448\" srcset=\"https:\/\/hosting175685eu-cp704.wordpresstemporal.com\/wp-content\/uploads\/2024\/10\/Captura-de-pantalla-2024-10-31-a-las-12.19.13.png 970w, https:\/\/hosting175685eu-cp704.wordpresstemporal.com\/wp-content\/uploads\/2024\/10\/Captura-de-pantalla-2024-10-31-a-las-12.19.13-300x139.png 300w, https:\/\/hosting175685eu-cp704.wordpresstemporal.com\/wp-content\/uploads\/2024\/10\/Captura-de-pantalla-2024-10-31-a-las-12.19.13-768x355.png 768w, https:\/\/hosting175685eu-cp704.wordpresstemporal.com\/wp-content\/uploads\/2024\/10\/Captura-de-pantalla-2024-10-31-a-las-12.19.13-350x162.png 350w\" sizes=\"(max-width: 970px) 100vw, 970px\" \/><\/h5>\n<p style=\"text-align: center;\"><b>Figure 5<\/b> &#8211; Water droplets on top of coated paper with a) resin 1 b) resin 2 with 2 and 3% of wax emulsions respectively.<\/p>\n<p><img decoding=\"async\" class=\"size-full wp-image-160701 aligncenter\" src=\"https:\/\/concentrol.com\/wp-content\/uploads\/2024\/10\/Captura-de-pantalla-2024-10-31-a-las-12.24.18.png\" alt=\"\" width=\"1112\" height=\"1132\" srcset=\"https:\/\/hosting175685eu-cp704.wordpresstemporal.com\/wp-content\/uploads\/2024\/10\/Captura-de-pantalla-2024-10-31-a-las-12.24.18.png 1112w, https:\/\/hosting175685eu-cp704.wordpresstemporal.com\/wp-content\/uploads\/2024\/10\/Captura-de-pantalla-2024-10-31-a-las-12.24.18-295x300.png 295w, https:\/\/hosting175685eu-cp704.wordpresstemporal.com\/wp-content\/uploads\/2024\/10\/Captura-de-pantalla-2024-10-31-a-las-12.24.18-1006x1024.png 1006w, https:\/\/hosting175685eu-cp704.wordpresstemporal.com\/wp-content\/uploads\/2024\/10\/Captura-de-pantalla-2024-10-31-a-las-12.24.18-768x782.png 768w, https:\/\/hosting175685eu-cp704.wordpresstemporal.com\/wp-content\/uploads\/2024\/10\/Captura-de-pantalla-2024-10-31-a-las-12.24.18-350x356.png 350w\" sizes=\"(max-width: 1112px) 100vw, 1112px\" \/><\/p>\n<p><b>Conclusions\u00a0<\/b><\/p>\n<p>EMULTROL CM-2469 SPL and EMULTROL CM-2655 E are paraffin wax emulsions, especially developed for waterborne coatings. Designed with two different emulsifying systems to increase the compatibility with typically aqueous resins used for this purpose. The main benefit of using those wax emulsions in water-based coatings is to increase the film hydrophobicity. The effectiveness of these wax emulsions is demonstrated in this study.<\/p>\n<p>Keep in mind that every formulation is unique and may require compatibility tests to ensure optimal results.<\/p>\n<h5 style=\"text-align: center;\">AUTHOR: Carlota Claras\u00f3<\/h5>\n<p>[\/vc_column_text][\/vc_column][\/vc_row][vc_row][vc_column column_width_percent=&#8221;100&#8243; gutter_size=&#8221;3&#8243; overlay_alpha=&#8221;50&#8243; shift_x=&#8221;0&#8243; shift_y=&#8221;0&#8243; shift_y_down=&#8221;0&#8243; z_index=&#8221;0&#8243; medium_width=&#8221;0&#8243; mobile_width=&#8221;0&#8243; width=&#8221;1\/1&#8243; uncode_shortcode_id=&#8221;114180&#8243;][vc_single_image media=&#8221;160711&#8243; media_width_percent=&#8221;100&#8243; uncode_shortcode_id=&#8221;131857&#8243;][\/vc_column][\/vc_row]<\/p>\n<\/div>","protected":false},"excerpt":{"rendered":"<p>[vc_row][vc_column][ [&hellip;]<\/p>\n","protected":false},"author":36,"featured_media":160713,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"_acf_changed":false,"content-type":"","footnotes":""},"categories":[275],"tags":[810,1147],"class_list":["post-160718","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-news","tag-concentrol-zh-hans","tag-wax-emulsion-zh-hans"],"acf":[],"yoast_head":"<!-- This site is optimized with the Yoast SEO plugin v28.0 - https:\/\/yoast.com\/product\/yoast-seo-wordpress\/ -->\n<title>Improving hydrophobicity of waterborne coatings with wax emulsion additives\u00a0 - Concentrol<\/title>\n<meta name=\"description\" content=\"Silicone Stabilizers for HR Molded Foams. 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