{"id":172839,"date":"2026-09-04T11:16:01","date_gmt":"2026-09-04T09:16:01","guid":{"rendered":"https:\/\/concentrol.com\/silicone-surfactants-recycled-polyol-pu-foams\/"},"modified":"2026-09-04T11:56:17","modified_gmt":"2026-09-04T09:56:17","slug":"silicone-surfactants-recycled-polyol-pu-foams","status":"publish","type":"post","link":"https:\/\/hosting175685eu-cp704.wordpresstemporal.com\/zh-hans\/silicone-surfactants-recycled-polyol-pu-foams\/","title":{"rendered":"EVALUATION OF SILICONE SURFACTANTS FOR FLEXIBLE POLYURETHANE FOAMS FORMULATED WITH RECYCLED POLYOLS"},"content":{"rendered":"<div class=\"wpb-content-wrapper\"><p>[vc_row][vc_column][vc_custom_heading text_size=&#8221;h4&#8243; uncode_shortcode_id=&#8221;361539&#8243;]<\/p>\n<h2><strong>Introduction<\/strong><\/h2>\n<p>[\/vc_custom_heading][vc_column_text uncode_shortcode_id=&#8221;205265&#8243;]<\/p>\n<p class=\"PDq2pG_selectionAnchorContainer\" data-start=\"279\" data-end=\"626\">The incorporation of <strong data-start=\"300\" data-end=\"353\">recycled polyols into flexible polyurethane foams<\/strong> represents a promising approach to <strong data-start=\"389\" data-end=\"441\">reducing the consumption of virgin raw materials<\/strong> and moving towards more circular production models. However, the <strong data-start=\"507\" data-end=\"531\">chemical variability<\/strong> of these materials can affect formulation compatibility, foam stability, and final properties.<\/p>\n<p data-start=\"628\" data-end=\"921\">In this study, <strong data-start=\"643\" data-end=\"712\">four silicone surfactants (E0329_1, E0329_2, E0329_3 and E0329_4)<\/strong> designed for flexible slabstock formulations containing recycled polyol were evaluated. <strong data-start=\"801\" data-end=\"906\">Compatibility, stability, cell regulation, density, hardness (CLD), airflow, and compression set (CS)<\/strong> were analyzed.<\/p>\n<p>[\/vc_column_text][\/vc_column][\/vc_row][vc_row][vc_column][vc_custom_heading heading_semantic=&#8221;h3&#8243; text_size=&#8221;h4&#8243; uncode_shortcode_id=&#8221;104132&#8243;]<\/p>\n<h2><strong>Objective<\/strong><\/h2>\n<p>[\/vc_custom_heading][vc_column_text uncode_shortcode_id=&#8221;425977&#8243;]To develop and select a <strong data-start=\"961\" data-end=\"1049\">suitable silicone surfactant for flexible foam formulations based on recycled polyol<\/strong>, ensuring a balance between <strong data-start=\"1078\" data-end=\"1153\">stability, cell regulation, air permeability, and mechanical properties<\/strong>.[\/vc_column_text][\/vc_column][\/vc_row][vc_row][vc_column][vc_custom_heading uncode_shortcode_id=&#8221;193184&#8243;]<\/p>\n<h2><strong>Methodology<\/strong><\/h2>\n<p>[\/vc_custom_heading][vc_column_text uncode_shortcode_id=&#8221;162775&#8243;]<\/p>\n<h3 class=\"PDq2pG_selectionAnchorContainer\" data-section-id=\"ofzh8j\" data-start=\"1172\" data-end=\"1185\">Stability<\/h3>\n<p class=\"\" data-start=\"1187\" data-end=\"1407\">Visual compatibility tests were carried out using a PU formulation with <strong data-start=\"1259\" data-end=\"1287\">each surfactant (1 pphp)<\/strong>, evaluating the <strong data-start=\"1304\" data-end=\"1406\">initial state, after 24 hours at room temperature, and after accelerated aging for 7 days at 50 \u00b0C<\/strong>.<\/p>\n<table style=\"height: 171px;\" width=\"385\">\n<thead>\n<tr>\n<th>Component<\/th>\n<th align=\"right\">Pphp<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>Polyol OH=48<\/td>\n<td align=\"right\">75<\/td>\n<\/tr>\n<tr>\n<td>Recycled polyol<\/td>\n<td align=\"right\">25<\/td>\n<\/tr>\n<tr>\n<td>H2O<\/td>\n<td align=\"right\">5<\/td>\n<\/tr>\n<tr>\n<td>TEDA<\/td>\n<td align=\"right\">0.15<\/td>\n<\/tr>\n<tr>\n<td>DMEE<\/td>\n<td align=\"right\">0.05<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<p>&nbsp;<\/p>\n<p>Subsequently, <strong data-start=\"1547\" data-end=\"1574\">free-rise foaming tests<\/strong> were carried out on slabstock formulations containing <strong data-start=\"1629\" data-end=\"1660\">25% and 50% recycled polyol<\/strong>. Foam stability, cell structure, hardness (CLD), density, airflow, and compression set were evaluated.[\/vc_column_text][\/vc_column][\/vc_row][vc_row][vc_column][vc_custom_heading uncode_shortcode_id=&#8221;149308&#8243;]<\/p>\n<h2><strong>Results and Discussion<\/strong><\/h2>\n<p>[\/vc_custom_heading][vc_single_image media=&#8221;172785&#8243; media_width_percent=&#8221;100&#8243; uncode_shortcode_id=&#8221;259917&#8243;][vc_column_text uncode_shortcode_id=&#8221;420903&#8243;]<\/p>\n<h6><em>Figure 1: Initial test<\/em><\/h6>\n<p>[\/vc_column_text][vc_single_image media=&#8221;172791&#8243; media_width_percent=&#8221;100&#8243; uncode_shortcode_id=&#8221;995767&#8243;][vc_column_text uncode_shortcode_id=&#8221;195573&#8243;]<\/p>\n<h6>Figure 2: 24 h at room temperature<\/h6>\n<p>[\/vc_column_text][vc_single_image media=&#8221;172797&#8243; media_width_percent=&#8221;100&#8243; uncode_shortcode_id=&#8221;210865&#8243;][vc_column_text uncode_shortcode_id=&#8221;106996&#8243;]<\/p>\n<h6>Figure 3: Aging test at 50 \u00b0C<\/h6>\n<p>[\/vc_column_text][vc_column_text uncode_shortcode_id=&#8221;420903&#8243;]The compatibility tests showed <strong data-start=\"1926\" data-end=\"1972\">good initial stability for all surfactants<\/strong>. After accelerated aging, most showed <strong data-start=\"2011\" data-end=\"2036\">some phase separation<\/strong>, indicating that severe conditions can affect the stability of the formulated system.[\/vc_column_text][vc_custom_heading uncode_shortcode_id=&#8221;113402&#8243;]<strong>Foams<\/strong>[\/vc_custom_heading][vc_single_image media=&#8221;172803&#8243; media_width_percent=&#8221;100&#8243; uncode_shortcode_id=&#8221;148614&#8243;][vc_column_text uncode_shortcode_id=&#8221;168149&#8243;]<\/p>\n<h6>Figure 4: Foams with 25% recycled polyol<\/h6>\n<p>[\/vc_column_text][vc_column_text uncode_shortcode_id=&#8221;420903&#8243;]In formulations containing <strong data-start=\"2208\" data-end=\"2279\">25% recycled polyol, all candidates provided adequate stabilization<\/strong>. Clear differences were observed in <strong data-start=\"2316\" data-end=\"2356\">air permeability and cell regulation<\/strong>. <strong data-start=\"2358\" data-end=\"2428\">E0329_4 showed the highest breathability and a more open structure<\/strong>, whereas <strong data-start=\"2438\" data-end=\"2483\">E0329_2 exhibited a more closed structure<\/strong>.[\/vc_column_text][vc_single_image media=&#8221;172809&#8243; media_width_percent=&#8221;100&#8243; uncode_shortcode_id=&#8221;823596&#8243;][vc_column_text uncode_shortcode_id=&#8221;581091&#8243;]<\/p>\n<h6>Figure 5: CLD values in formulation with 50% recycled polyol<\/h6>\n<p>[\/vc_column_text][vc_column_text uncode_shortcode_id=&#8221;420903&#8243;]With <strong data-start=\"2591\" data-end=\"2642\">50% recycled polyol, no collapses were observed<\/strong>, confirming the stabilizing capacity of all candidates. The CLD results indicated different levels of firmness among the surfactants. <strong data-start=\"2777\" data-end=\"2817\">E0329_1 generated the highest values<\/strong>, while <strong data-start=\"2825\" data-end=\"2858\">E0329_4 produced softer foams<\/strong>. <strong data-start=\"2860\" data-end=\"2931\">E0329_3 stood out for its finer and more homogeneous cell structure<\/strong>.[\/vc_column_text][vc_single_image media=&#8221;172815&#8243; media_width_percent=&#8221;100&#8243; uncode_shortcode_id=&#8221;175023&#8243;][vc_column_text uncode_shortcode_id=&#8221;208586&#8243;]<\/p>\n<h6>Figure 6: Internal cell structure, 50% recycled polyol<\/h6>\n<p>[\/vc_column_text][vc_column_text uncode_shortcode_id=&#8221;420903&#8243;]Likewise, E0329_2, E0329_3 and E0329_4 showed similar behavior in terms of airflow and open cells. Compression set results were acceptable for all formulations, with <strong data-start=\"3160\" data-end=\"3219\">E0329_1 and E0329_3 standing out for their lower values<\/strong>, indicating <strong data-start=\"3232\" data-end=\"3269\">better recovery after compression<\/strong>.[\/vc_column_text][vc_single_image media=&#8221;172821&#8243; media_width_percent=&#8221;100&#8243; uncode_shortcode_id=&#8221;138456&#8243;][vc_custom_heading uncode_shortcode_id=&#8221;815683&#8243;]<strong>Conclusions<\/strong>[\/vc_custom_heading][vc_column_text uncode_shortcode_id=&#8221;420903&#8243;]<\/p>\n<ul>\n<li data-section-id=\"1g1fzdx\" data-start=\"3464\" data-end=\"3578\"><strong data-start=\"3466\" data-end=\"3534\">All evaluated surfactants showed adequate stabilization capacity<\/strong> in formulations containing recycled polyol.<\/li>\n<li data-section-id=\"zwb8tm\" data-start=\"3580\" data-end=\"3719\">Compatibility was satisfactory under standard conditions, although <strong data-start=\"3649\" data-end=\"3718\">accelerated aging revealed some tendency towards phase separation<\/strong>.<\/li>\n<li data-section-id=\"1f0a1ch\" data-start=\"3721\" data-end=\"3796\"><strong data-start=\"3723\" data-end=\"3796\">E0329_4 stood out for its high breathability and open-cell character.<\/strong><\/li>\n<li data-section-id=\"7pjol7\" data-start=\"3798\" data-end=\"3913\"><strong data-start=\"3800\" data-end=\"3865\">E0329_3 showed the finest and most homogeneous cell structure<\/strong> in formulations containing 50% recycled polyol.<\/li>\n<li data-section-id=\"3ji4k2\" data-start=\"3915\" data-end=\"4075\">The results confirm that <strong data-start=\"3942\" data-end=\"4074\">surfactant selection is a key factor in optimizing the performance of sustainable flexible foams based on recycled raw materials<\/strong>.<\/li>\n<\/ul>\n<p>[\/vc_column_text][vc_column_text uncode_shortcode_id=&#8221;190766&#8243;]<\/p>\n<h6>Figure 7: Densities and breathability, 50% recycled polyol<\/h6>\n<p>[\/vc_column_text][\/vc_column][\/vc_row]<\/p>\n<\/div>","protected":false},"excerpt":{"rendered":"<p>[vc_row][vc_column][ [&hellip;]<\/p>\n","protected":false},"author":36,"featured_media":172831,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"_acf_changed":false,"content-type":"","footnotes":""},"categories":[1023,286],"tags":[1339,1342,1338,1153,1340,1341],"class_list":["post-172839","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-pu-additives-zh-hans","category-research-blog-zh-hans","tag-flexible-pu-foam","tag-foam-stability","tag-recycled-polyols","tag-silicone-surfactants","tag-slabstock-foam","tag-sustainable-polyurethane"],"acf":[],"yoast_head":"<!-- This site is optimized with the Yoast SEO plugin v28.4 - https:\/\/yoast.com\/product\/yoast-seo-wordpress\/ -->\n<title>Silicone Surfactants for Flexible PU Foams with Recycled Polyols<\/title>\n<meta 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